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Pd-Catalyzed Alkynylation of 2-Chloroacetates and 2-Chloroacetamides with Potassium Alkynyltrifluoroborates

✍ Scribed by Molander, Gary A.; Traister, Kaitlin M.

Book ID: 121192163
Publisher: American Chemical Society
Year: 2013
Tongue: English
Weight: 520 KB
Volume: 15
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol402391z

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## Abstract Isoquinoline‐4‐carboxylic esters **3** and isochromene‐4‐carboxylic esters **4** have been conveniently prepared by direct PdI~2~‐catalyzed oxidative heterocyclization/alkoxycarbonylation of readily available (2‐alkynylbenzylidene)amine derivatives. In particular, (2‐alkynylbenzylidene)