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pBa2Cu3O7-x superconductors via oxide precursor containing BaCuO2.5

โœ Scribed by Hai-poong Park; Shome N. Sinha


Book ID
103984432
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
617 KB
Volume
1
Category
Article
ISSN
0964-1807

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โœฆ Synopsis


An oxide precursor (NEPTH) comprising 0.5 Y,OJ + CuO + ZBaCuO,,, is used to synthesize bulk YBa,Cu,O,_, superconductor. By thermomechanical processing of a silver tube packed with the precursor at 950ยฐC for less than 9Omin, and subsequently cooling in air at less than ZOOCjh, orthorhombic YBa,Cu,O,_ X phase is directly obtained. For processing at 950 and 9OO"C, the superconducting properties are correlated with the pertinent process parameters.


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Formation of orthorhombic YBa2Cu3O7โˆ’x at
โœ Shome N. Sinha; Hai Woong Park ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 910 KB

Orthorhombic YBa2Cu3OT\_x was obtained when a synthesized precursor containing Y203, BaCuO2.5 and CuO was heated rapidly to 950-1020ยฐC in air, held for 30 min, and quenched. During DTA at 20ยฐC/min, the BaCuO2.5 in the precursor decomposed at 838ยฐC. The BaCuO2.5 constituent did not completely decompo