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[Pb5{Mo(CO)3}2]4-: A Complex Containing a Planar Pb5 Unit.

✍ Scribed by Li Yong; Stephan D. Hoffmann; Thomas F. Faessler; Sebastian Riedel; Martin Kaupp

Publisher
John Wiley and Sons
Year
2005
Weight
17 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract The reaction of [Mo(CO)~3~(MeCN)~3~] with K~4~Pb~9~ in the presence of 2.2.2‐cryptand (2.2.2‐crypt) has been investigated. The transition metal complex [K(2.2.2‐crypt)]~4~[(η^5^__‐__Pb~9~)Mo(CO)~3~] (1), which contains a Pb~9~^4–^ Zintl anion coordinated by Mo in an η^5^‐fashion, is iso

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