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Pb2+ cation ordering in Pb3(Mo4O6)4

✍ Scribed by Wang, S. L. ;Yeh, J. Y.

Book ID
114514727
Publisher
International Union of Crystallography
Year
1991
Tongue
English
Weight
721 KB
Volume
47
Category
Article
ISSN
0108-7681

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✍ Li Yong; Stephan D. Hoffmann; Thomas F. Fässler 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 214 KB 👁 1 views

## Abstract The reaction of [Mo(CO)~3~(MeCN)~3~] with K~4~Pb~9~ in the presence of 2.2.2‐cryptand (2.2.2‐crypt) has been investigated. The transition metal complex [K(2.2.2‐crypt)]~4~[(η^5^__‐__Pb~9~)Mo(CO)~3~] (1), which contains a Pb~9~^4–^ Zintl anion coordinated by Mo in an η^5^‐fashion, is iso