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Pathways of ion–molecular interactions of nucleogenic phenyl cations with the nucleophilic centers of picolines

✍ Scribed by Nadezhda E Shchepina, Viktor V Avrorin, Gennady A Badun, Nikolay A Bumagin, Scott B Lewis, Sergey N Shurov

Book ID: 119915278
Publisher: Springer-Verlag
Year: 2012
Tongue: English
Weight: 165 KB
Volume: 2
Category: Article
ISSN: 2191-2858
DOI: 10.1186/2191-2858-2-14

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## Abstract A kinetic study of the nucleophilic substitution reaction of Y‐substituted phenyl diphenylphosphinothioates **2 a**–**g** with alkali‐metal ethoxides (MOEt; M=Li, Na, K) in anhydrous ethanol at (25.0±0.1) °C is reported. Plots of pseudo‐first‐order rate constants (__k__~obsd~) versus [M