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Pathways of excess electron transfer in phenothiazine-tethered DNA containing single-base mismatches

✍ Scribed by Ito, Takeo; Kondo, Akiko; Kamashita, Tomoyuki; Tanabe, Kazuhito; Yamada, Hisatsugu; Nishimoto, Sei-ichi

Book ID: 118272439
Publisher: Royal Society of Chemistry
Year: 2009
Tongue: English
Weight: 182 KB
Volume: 7
Category: Article
ISSN: 1477-0520
DOI: 10.1039/b820311c

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## Abstract Oxetane is a potential intermediate that is enzymatically formed during the repair of (6–4) DNA lesions by special repair enzymes (6–4 DNA photolyases). These enzymes use a reduced and deprotonated flavin to cleave the oxetane by single electron donation. Herein we report synthesis of D