✦ LIBER ✦

Pathways of Electrochemical Oxidation of Indolic Compounds

✍ Scribed by Teodor Adrian Enache; Ana Maria Oliveira-Brett

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 269 KB
Volume: 23
Category: Article
ISSN: 1040-0397
DOI: 10.1002/elan.201000671

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✦ Synopsis

Abstract

The electrochemical behaviour of indole and a group of indole‐containing compounds with a substituent at the C3 position, indol‐3‐acetamide (IAM), tryptamine, gramine, indole acetic acid (IAA), indole propionic acid (IPA), indole butyric acid (IBA) and tryptophan, was investigated at a glassy carbon electrode, in order to determine their oxidation pathways. Indole undergoes one irreversible pH dependent oxidation, whereas the oxidation process of indole derivatives was more complex, a two step, the oxidation at C2 position on the pyrrole ring followed by the hydroxylation at the C7 position of the benzene moiety of indoles, irreversible pH dependent oxidation.

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