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Pathways for nucleophilic substitution at silicon. A molecular orbital approach

✍ Scribed by Deiters, Joan A.; Holmes, Robert R.


Book ID
120044930
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
884 KB
Volume
109
Category
Article
ISSN
0002-7863

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## Abstract To obtain a set of consistent benchmark potential energy surfaces (PES) for the two archetypal nucleophilic substitution reactions of the chloride anion at carbon in chloromethane (S~N~2@C) and at silicon in chlorosilane (S~N~2@Si), we have explored these PESes using a hierarchical seri