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Paths of conversion of aminyl radicals of the tetrahydroquinoline series upon interaction with peroxy radicals

✍ Scribed by O. T. Kasaikina; T. V. Lobanova; D. V. Fentsov


Book ID
112445997
Publisher
Springer
Year
1983
Tongue
English
Weight
339 KB
Volume
32
Category
Article
ISSN
1573-9171

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Reaction path calculations for the inter
✍ Chia-Chung Chen; Marye Anne Fox πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 English βš– 409 KB πŸ‘ 1 views

UMNDO reaction path calculations for trapping of the ethylene-cation radical with ground state oxygen suggest that formation of a dioxetane radical cation proceeds through the intermediacy of a peroxycation radical. The predicted enthalpy of activation (A€€% = 13.8 kcal/mol) is consistent with rapid