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Paterno-Büchi Reaction of 2-Morpholinoacrylonitrile with Benzil

✍ Scribed by Döpp, Dietrich ;Memarian, Hamid Reza ;Fischer, Michael Alexander ;Van Eijk, Alexander M. J. ;Varma, Cyril A. G. O.

Publisher
Wiley (John Wiley & Sons)
Year
1992
Tongue
English
Weight
249 KB
Volume
125
Category
Article
ISSN
0009-2940

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✦ Synopsis

In the lowest excited triplet state, benzil (1) adds highly regio‐ and stereoselectively to the olefin 2‐morpholinoacrylonitrile (2) to form solely the oxetane 5.

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