Many dilute solutions or suspensions of rod-like particles become birefringent when subjected to electric fields. On switching off the applied field the birefringence decays away as the particles revert from an ordered to a random orientation state. For polydisperse suspensions it is possible to ev
Particle size distribution from transient electric birefringence data: III. polydisperse ellipsoids by two-parameter distribution functions
โ Scribed by V.J. Morris; A.R. Foweraker; B.R. Jennings
- Publisher
- Elsevier Science
- Year
- 1978
- Weight
- 273 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0378-4487
No coin nor oath required. For personal study only.
โฆ Synopsis
The decay of the electrically induced transient birefringence, for a dilute polydis~erse suspension of ellipsoidally shaped particles of constant axial ratio, is analysed. It is shown that, for the decay process, the initial slopes of the natural logarithm of the normalised birefringence versus time curves for transients obtained under two discrete experimental conditions provide sufficient d~ta to describe the spread in particle size in terms of two-parameter distribution functions. The procedure is described for three common skew distributions and two symmetric ones. A simple procedure for identifying the most appropriate distribution function is given.
๐ SIMILAR VOLUMES
An analysis is presented for the decay process encountered in transient electric birefringence experiments. The method is developed for dilute and polydisperse suspensions of constant thickness disc-like particles. If the distribution function describing the spread in particle diameters is of a two