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Particle Formation in Precipitation Polymerization: Continuous Precipitation Polymerization of Acrylic Acid in Supercritical Carbon Dioxide

✍ Scribed by Liu, Tao; Garner, Pamela; DeSimone, Joseph M.; Roberts, George W.; Bothun, Geoffrey D.

Book ID
126294534
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
382 KB
Volume
39
Category
Article
ISSN
0024-9297

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## Abstract Nitroxide‐mediated controlled/living radical precipitation polymerization of styrene in supercritical carbon dioxide has been performed using SG1 and AIBN as mediator and initiator, respectively. The equivalent bulk polymerization proceeded at a rate β‰ˆ1.58 times faster than the precipit