Participation of a peri-hydroxyl group in the trifluoroacetolysis of naphthalenesulfonamides
โ Scribed by Jean-Paul Mazaleyrat; Michel Wakselman
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 205 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
In recent years solvolysis of 2-arylethyl arenesulfonates has been successfully discussed based on the idea that the reaction proceeds via two discrete and competing paths designated as k, and ks. 2-5 While electrondonating substituents accelerate the reaction mainly or almost exclusively by the an
Treatment of 2,3:4,5-di-g-isopropylidene-k-arabinose diphenyl dithioacetal (la) with sodium methylsulfinyl carbanion in DMSO has previously been shown2 to produce ga via extraction of the acidic C-l hydrogen and concomitant elimination of acetone. Workup of the reaction with water gave 2-deoxy-4,5-Q