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Partially Formed Bonds In HCN−SO 3 and CH 3 CN−SO 3 : A Comparison between Donor−Acceptor Complexes of SO 3 and BF 3

✍ Scribed by Burns, W. A.; Phillips, J. A.; Canagaratna, M.; Goodfriend, H.; Leopold, K. R.


Book ID
126130665
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
96 KB
Volume
103
Category
Article
ISSN
1089-5639

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The rotational spectrum of HCCCN-SO 3 has been observed using Fourier transform microwave spectroscopy. The vibrationally averaged structure is that of a symmetric top, with the HCCCN axis along the C 3 axis of the SO 3 , and the nitrogen end near the sulfur. The N-S bond length is 2.567(13) Å, whic