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Partially fluorinated maleimide copolymers for Langmuir films of improved stability, 1. Synthesis, copolymerisation behaviour and bulk properties

✍ Scribed by Moheddin El-Guweri; Peter Hendlinger; André Laschewsky


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
872 KB
Volume
198
Category
Article
ISSN
1022-1352

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✦ Synopsis


Abstract

Various new partially fluorinated polymers on the basis of substituted N‐phenylmaleimides are prepared by radical copolymerisation. Nearly alternating copolymers are produced with vinyl ethers and styrene derivatives. The copolymers show high stability against thermal degradation in comparison to conventional vinyl and vinylidene polymers, and high glass transition temperatures. Highest thermal stability is found for copolymers in which the classical hydrophilic and hydrophobic fragments are reduced to a minimum.