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Partially Bridge-Fluorinated Dimethyl Bicyclo[1.1.1]pentane-1,3-dicarboxylates: Preparation and NMR Spectra

✍ Scribed by Shtarev, Alexander B.; Pinkhassik, Evgueni; Levin, Michael D.; Stibor, Ivan; Michl, Josef


Book ID
120203556
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
98 KB
Volume
123
Category
Article
ISSN
0002-7863

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C3(SINGLE BOND)M? Bond contribution to p
✍ Giribet, C. G.; de AzοΏ½a, M. C. Ruiz; GοΏ½mez, S. B.; Botek, E. L.; Contreras, R. H πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 176 KB

In the present work, the relationship between the large substituent 3 Ž . w x effects on J C H in 1-X-3-M-bicyclo 1.1.1 pentanes, I, and the polarizability of 1 the bridgehead C -M bond is investigated. The existence of such a relationship 3 ␣ is suggested by the finding that the effect of an electr