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Partial oxidation of olefins by molecular oxygen catalysed by (alumina)Rh(O2). Part 2

✍ Scribed by Jeffrey Schwartz; Jeffrey W. McMillan; H. Eric Fischer


Publisher
Elsevier Science
Year
1992
Weight
468 KB
Volume
74
Category
Article
ISSN
0304-5102

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Treatment of several cyclic olefins and allylbenzene with a catalytic amount of [Rh30(OAc)6(H20)3]OAc in acetic acid in the presence of t-butvl hvdroperoxide affords the corresponding a,8-unsaturated carbonyl compounds highly selectively via an ionic pathway.

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