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Partial oxidation of methane to synthesis gas using carbon dioxide

โœ Scribed by Ashcroft, A. T.; Cheetham, A. K.; Green, M. L. H.; Vernon, P. D. F.


Book ID
109777652
Publisher
Nature Publishing Group
Year
1991
Tongue
English
Weight
220 KB
Volume
352
Category
Article
ISSN
0028-0836

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The partial oxidation of methane to synthesis gas has been studied using several different catalytic systems: Fixed-bed, a monolithic type catalyst, and a Pt gauze. The monoliths were impregnated with Ni and Pd (5 wt.% metal) whereas 5% Ni/ AI203 was used in the fixed-bed reactor. The experiments we

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Catalytic partial oxidation of methane to synthesis gas was performed over La-M-O, with M = Co, Cr, Ni, Rh. The best system, La-Rh-0, gave 95% conversion with 98% selectivity to carbon monoxide even after 120 h on stream at 800ยฐC. La-Ni-0 deactivated after about 17 h on stream, probably due to coke