Partial Gas Phase Hydrogenation of Benzene on Sol-Gel Ruthenium Catalysts
✍ Scribed by Jürgen Patzlaff; Johann Gaube
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 337 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0930-7516
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The solid-phase synthesis of new asymmetric transfer hydrogenation catalysts as well as the use of these silica supported systems in batch and flow reactors is reported. The ruthenium complex of NH-benzyl-(1R,2S)-(À)-norephedrine covalently tethered to silica showed a high activity and enantioselect
## Abstract The hydrogenation of dienes such as 1,3‐butadiene, cyclooctadiene, and of acetylenic hydrocarbons on Pd catalysts shows high reaction rates and consequently, a strong influence of mass transfer on the selectivity of the intermediate alkene or cycloalkene product. 100 % selectivity towar