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[Part 1: Physical Sciences] || Transfer Activity Coefficients between Water and Methanol of Complexes of Some Univalent and Barium Ions with Dibenzocryptand 2.2.2, Cryptand 2.2.2, and 18-Crown-6

✍ Scribed by Miran K. Chantooni and Izaak M. Kolthoff


Book ID
123623005
Publisher
National Academy of Sciences
Year
1981
Tongue
English
Weight
544 KB
Volume
78
Category
Article
ISSN
0027-8424

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Free energies of transfer from water to
✍ B.G. Cox; P. Firman; J. Garcia-Rosas; H. Schneider πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 242 KB

A complexation scheme involving a conformational equilibrium of the ligand is proposed to explain the difference in free energies of transfer between metal complex and ligand from water to non-aqueous solvents. In a recent paper Abraham and Ling' have reported the thermodynamic parameters of transf