We have analyzed the 1 u ( 1 D) and 2 u ( 1 D) ion-pair states of I 2 by perturbation-facilitated optical-optical double resonance using the B 3 (0 + u ) ∼ c1 g mixing state as an intermediate. The double-resonance spectra exhibited the strong vibrational progression to the 1 u ( 1 D) state in accor
✦ LIBER ✦
Parity Mixing in the Valence States of I2 Probed by Optical-Optical Double-Resonance Excitation of Ion-Pair: Characterization of a New Ion-Pair State, H1u(3P1), and a Valence State, c1g
✍ Scribed by P.J. Jewsbury; T. Ridley; K.P. Lawley; R.J. Donovan
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 774 KB
- Volume
- 157
- Category
- Article
- ISSN
- 0022-2852
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The optical-optical double-resonance spectroscopy is applied to study the ion-pair states of \(\mathrm{Cl}_{2}\) correlating to \(\mathrm{Cl}^{-}\left({ }^{1} S\right)+\mathrm{Cl}^{+}\left({ }^{3} P_{2}\right)\). In the \((1+2)\) photoexcitation sequence, we gain access to the \(0_{u}^{+}\left({ }^{