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Parametrized Valence Bond Studies of the Origin of the N−F Bond Lengthenings of FNO 2 and FNO

✍ Scribed by Harcourt, Richard D.; Wolynec, P. Peter

Book ID
126423415
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
77 KB
Volume
105
Category
Article
ISSN
1089-5639

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## Abstract For each of HNO, FNO, LiNO, LiON and HF~2~^−^, __ab initio__ valence‐bond wave functions are reported for the four‐electron three‐center bonding unit which involves one of the following sets of atomic orbitals: (a) N__X__ σ‐bond (__X__ = H, For Li) and oxygen 2__p__π′; (b) LiO σ‐bond an