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Parametric study of chemical looping combustion for tri-generation of hydrogen, heat, and electrical power with CO2 capture

✍ Scribed by J. Wolf; J. Yan


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
186 KB
Volume
29
Category
Article
ISSN
0363-907X

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✦ Synopsis


In this article, a novel cycle configuration has been studied, termed the extended chemical looping combustion integrated in a steam-injected gas turbine cycle. The products of this system are hydrogen, heat, and electrical power. Furthermore, the system inherently separates the CO 2 and hydrogen that is produced during the combustion. The core process is an extended chemical looping combustion (exCLC) process which is based on classical chemical looping combustion (CLC). In classical CLC, a solid oxygen carrier circulates between two fluidized bed reactors and transports oxygen from the combustion air to the fuel; thus, the fuel is not mixed with air and an inherent CO 2 separation occurs. In exCLC the oxygen carrier circulates along with a carbon carrier between three fluidized bed reactors, one to oxidize the oxygen carrier, one to produces and separate the hydrogen, and one to regenerate the carbon carrier. The impacts of process parameters, such as flowrates and temperatures have been studied on the efficiencies of producing electrical power, hydrogen, and district heating and on the degree of capturing CO 2 . The result shows that this process has the potential to achieve a thermal efficiency of 54% while 96% of the CO 2 is captured and compressed to 110 bar.