Paramagnetic resonance in bipyridyl adducts of copper(II) salicylhydroxamates

✍ Scribed by Padmakar V. Khadikar; Taghi Ghadrian

• Publisher: John Wiley and Sons
• Year: 1993
• Tongue: English
• Weight: 383 KB
• Volume: 31
• Category: Article
• ISSN: 0749-1581
• DOI: 10.1002/mrc.1260310803

✦ Synopsis

Abstract

ESR spectra of bipyridyl(Bipy) adducts of copper(II) salicylhydroxamates were obtained at room and liquid nitrogen temperatures in polycrystalline samples. The bonding ability of Bipy is discussed on the basis of N‐superhyperfine coupling (N‐Shf) while the magnitude of CuL bonding is discussed on the basis of ESR parameters. The room temperature magnetic moment values indicated tetragonal distortion. The nature of distortion is also discussed on the basis of N‐Shf coupling.