Paramagnetic reaction products of bis(1,3,5-tri-tert-butyl-2,5-cyclohexadien-4-one) 1-peroxide with the halides of aluminum, gallium, and indium
✍ Scribed by G. A. Abakumov; E. S. Klimov; V. A. Muraev; G. A. Razuvaev
- Book ID
- 112423003
- Publisher
- Springer
- Year
- 1972
- Tongue
- English
- Weight
- 335 KB
- Volume
- 21
- Category
- Article
- ISSN
- 1573-9171
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## Abstract Treatment of the lithium amide Li[NPh(SiMe~3~)] with 2,4,6‐tri‐__tert__‐butyl‐1,3,5‐triphosphabenzene, P~3~C~3~__t__Bu~3~, in a 1:2 ratio afforded equimolar amounts of the lithium salt of the five‐membered 2,4,5‐tri‐__tert__‐butyl‐1,3‐diphospholide anion, LiP~2~C~3~__t__Bu~3~ (isolated
6-Tri-tert-butyl-1,3,5-triphosphabenzene 4 reacts with to the 1,3,4,7-tetraphosphasemibullvalene derivative 10 as the only product. The single-crystal X-ray analysis of 10 phosphaalkynes PϵCϪR [R = tBu (5a), tPen (5b)] at room temperature in a formal [4 + 2] cycloaddition to yield the exhibits a dip