Paramagnetic Radicals in Nitrate Doped Potassium Chloride

✍ Scribed by D. Schoemaker; E. Boesman

• Book ID: 105385640
• Publisher: John Wiley and Sons
• Year: 1963
• Tongue: English
• Weight: 542 KB
• Volume: 3
• Category: Article
• ISSN: 0370-1972
• DOI: 10.1002/pssb.19630030914

✦ Synopsis

Abstract

This study concerns two paramagnetic resonance spectra found at room temperature in X‐ray irradiated KCl doped in the melt with KNO~3~. One spectrum could be ascribed to a NO molecule, probably in an anion vacancy, and the other to a N molecular ion in an anion vacancy, both having approximately axial symmetry around a [100] direction. An unidentified resonance found by SANDER [5], is also discussed. This resonance is considered to be due to centres formed by N^−^ molecular ions in anion vacancies and having orthorhombic symmetry with [001], [110] and [110] axes.