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Parallel solid-phase synthesis, screening, and encoding strategies for olefin-polymerization catalysts

✍ Scribed by Thomas R. Boussie; Vince Murphy; Keith A. Hall; Carla Coutard; Cameron Dales; Miroslav Petro; Eric Carlson; Howard W. Turner; Timothy S. Powers


Book ID
104209611
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
638 KB
Volume
55
Category
Article
ISSN
0040-4020

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✦ Synopsis


A solid-phase protocol has been developed that allows for the parallel synthesis, screening, and chemical encoding of nickel (II) and palladium (II) olefinpolymerization catalysts. These catalysts display activity profiles comparable to the analogous homogeneous catalyst systems prepared by traditional methods. A chemical encoding strategy has also been developed which enables the chemical history of pooled solid-phase catalysts to be evaluated.


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