𝔖 Bobbio Scriptorium

✦ LIBER ✦

Parallel Modes of C−H Bond Activation Initiated by Cp*Mo(NO)(CH 2 CMe 3 )(C 6 H 5 ) at Ambient Temperatures 1

✍ Scribed by Wada, Kenji; Pamplin, Craig B.; Legzdins, Peter

Book ID: 126982292
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 74 KB
Volume: 124
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja027080m

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Facile and Selective Aliphatic C−H Bond

Facile and Selective Aliphatic C−H Bond Activation at Ambient Temperatures Initiated by Cp*W(NO)(CH 2 CMe 3 )(η 3 -CH 2 CHCHMe)

✍ Tsang, Jenkins Y. K.; Buschhaus, Miriam S. A.; Graham, Peter M.; Semiao, Christo 📂 Article 📅 2008 🏛 American Chemical Society 🌐 English ⚖ 409 KB

Helical Supramolecular Assemblies of {2,

Helical Supramolecular Assemblies of {2,4,6-[Cp∗Rh(E 2 -1,2-C 2 B 10 H 10 )(NC 5 H 4 CH 2 S)] 3 (triazine)} (E = S, Se) Shaped by Cp∗−Toluene−Cp∗ π-Stacking Forces and BH−Pyridine Hydrogen Bonding

✍ Wang, Guo-Liang; Lin, Yue-Jian; Blacque, Olivier; Berke, Heinz; Jin, Guo-Xin 📂 Article 📅 2008 🏛 American Chemical Society 🌐 English ⚖ 897 KB

Formation of .eta.1-iminoacyl compounds

Formation of .eta.1-iminoacyl compounds by insertion of isonitriles into pentamethylcyclopentadienyl-tetramethylfulvene compounds of titanium and zirconium. Intramolecular C-H activation of a pentamethylcyclopentadienyl group to give a tridentate ligand with two bridged cyclopentadienyl rings and a titanium-vinyl bond in the bridge. Molecular structure of [cyclic][.eta.5:.eta.1:.eta.5-C5Me4CH2C(NHXyl):CN(Xyl)CH2C5Me4]TiCl and [cyclic]Cp*[.eta.5:.eta.1-C5Me4CH2C(:NXyl)C(:NXyl)]ZrCl (Xyl=2,6-Me2C6H3)

✍ Fandos, Rosa.; Meetsma, Auke.; Teuben, Jan H. 📂 Article 📅 1991 🏛 American Chemical Society 🌐 English ⚖ 916 KB

Oxygenate, oxyalkyl and alkoxycarbonyl t

Oxygenate, oxyalkyl and alkoxycarbonyl thermochemistry and rates for hydrogen abstraction from oxygenatesElectronic supplementary information (ESI) available: Supplementary Table A: The MP2/6-31G(d?) optimized Cartesian coordinates (in ?), the unscaled harmonic vibrational frequencies (in cm?1) and rotational CONSTS (in GHz) at the HF/6-31G(d?) level of the transition structures involved in the abstraction by H atom from the methoxy, primary and secondary alkoxy, carbonyl and hydroperoxy hydrogens. Supplementary Table B: The MP2/6-31G(d?) optimized Cartesian coordinates (in ?), the unscaled harmonic vibrational frequencies (in cm?1) and rotational constants (in GHz) at the HF/6-31G(d?) level of the transition structures involved in the abstraction by CH3 group from the methoxy, primary and secondary alkoxy, carbonyl and hydroperoxy hydrogens. Supplementary Table C: Number of minima on the one-dimensional rotational potential energy surface and the relative energies (in kcal mol?1) of minima together with the total barrier height (in kcal mol?1) for rotation around the specified bond at the HF/6-31G(d?) level. See http://www.rsc.org/suppdata/cp/b3/b307050f/

✍ Sumathi, R.; Green, Jr., William H. 📂 Article 📅 2003 🏛 Royal Society of Chemistry 🌐 English ⚖ 345 KB