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Parallel mechanistic studies on the counterion effect of manganese salen and porphyrin complexes on olefin epoxidation by iodosylarenes

✍ Scribed by Se-Eun Park; Woon Ju Song; Yon Ok Ryu; Mi Hee Lim; Rita Song; Kwan Mook Kim; Wonwoo Nam


Book ID
108174827
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
408 KB
Volume
99
Category
Article
ISSN
0162-0134

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A systematic study on the kinetics and mechanism of oxidation of several (para-substituted phenylthio)acetic acids with various substituted oxo(salen)manganese(V) complexes in acetonitrile at 20 β€’ C is presented. The kinetic data indicate that the reaction is second-order overall, firstorder each in