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Parallel kinetic resolution of racemic mixtures: a new strategy for the preparation of enantiopure compounds?

✍ Scribed by Dehli, Juan R.; Gotor, Vicente

Book ID
115446911
Publisher
Royal Society of Chemistry
Year
2002
Tongue
English
Weight
252 KB
Volume
31
Category
Article
ISSN
0306-0012

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Resolution of racemic carboxylic acid de
Resolution of racemic carboxylic acid derivatives by Ti-TADDOLate mediated esterification reactionsβ€”A general method for the preparation of enantiopure compounds
✍ Dieter Seebach; Georg Jaeschke; Konstanze Gottwald; Keiji Matsuda; Roberto Formi πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 909 KB

The Lewis-acid mediated transfer of an alkoxide ligand from the chiral ligand sphere of Ti-TADDOLates ! to cyclic carboxylic acid derivatives is described. The kinetic resolution of dioxolanones, azlactones and biaryl lactones by the Ti-TADDOLates affords, after recrystallization, ester products in