Parallel Kinetic Resolution Approach to
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Laura C. Miller; J. Maina Ndungu; Richmond Sarpong
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Article
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2009
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John Wiley and Sons
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English
⚖ 346 KB
## Abstract **Parallel effort**: Stereodivergent parallel kinetic resolution of a racemic mixture of dienes using Davies' [Rh~2~{(__S__)‐dosp}~4~] or [Rh~2~{(__R__)‐dosp}~4~] catalysts promotes a tandem vinyl diazoacetate cyclopropanation/Cope rearrangement sequence to afford two diastereomeric, en