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Parallel acetalation reactions during the alcoholysis of poly(vinyl acetate) to poly(vinyl alcohol)

✍ Scribed by A. Krause; H. Marschner; D. Reiss-Wunderling; K. Schlothauer; B. Lebek

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
277 KB
Volume
39
Category
Article
ISSN
0323-7648

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✦ Synopsis

Acta Polymerica 39 (1988) Nr. 12 724 KRAUSE, MARSCHNER et al. : Parallel acetalation reactions during the alcoholysis of poly(viny1 acetate)

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A kinetic study was carried out on the acetalization reaction of 1,3-butanediol, as a model compound for poly(vinyl alcohol) (PVA), in water, under acidic conditions. Since these equilibrium constants of ketalization reaction of 1,3-butanediol and ethylene glycol are so small, the kinetic parameters