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Paraffin dehydrocyclization. Competitive conversion of paraffins and naphthenes

โœ Scribed by Burtron H. Davis


Book ID
113174184
Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
698 KB
Volume
23
Category
Article
ISSN
0021-9517

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Paraffin Dehydrocyclization: Isotope Eff
โœ Yuguo Wang; Buchang Shi; Robert D. Guthrie; Burtron H. Davis ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 147 KB

The kinetic isotope effect and the lack of deuterium-hydrogen exchange in the unconverted reactants show that chemisorption of the reactant is the slow step of the dehydrocyclization mechanism with a Pt-SiO 2 catalyst. While the chemisorption was nearly irreversible for a Pt-SiO 2 catalyst, this was