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Paracyclophane phenols and derivatives. I. Synthesis and pKA values of 4-hydroxy- and 4-amino[2.2]paracyclophane

✍ Scribed by Norcross, Bruce E.; Becker, David; Cukier, Robert I.; Schultz, Richard M.


Book ID
126979334
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
472 KB
Volume
32
Category
Article
ISSN
0022-3263

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Asymmetric synthesis of (R,S)- and (R,R)
✍ Elena V Sergeeva; Valeria I Rozenberg; Evgenii V Vorontsov; Tat'yana I Danilova; πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 548 KB

Highly diastereoselective nucleophilic addition reactions of organometallic reagents to formyl[2.2]paracyclophane derivatives which were ortho-substituted by hydroxy-, alkoxy-and trimethylsilyloxy-groups are reported. The absolute configuration of the newly formed secondary alcohols is assigned on t