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para-Functionalized NCN-Pincer Palladium(II) Complexes: Synthesis, Catalysis and DFT Calculations

✍ Scribed by Harm P. Dijkstra; Martijn Q. Slagt; Aidan McDonald; Cornelis A. Kruithof; Robert Kreiter; Allison M. Mills; Martin Lutz; Anthony L. Spek; Wim Klopper; Gerard P. M. van Klink; Gerard van Koten

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
181 KB
Volume
2003
Category
Article
ISSN
1434-1948

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Synthesis and Properties of para-Substit
Synthesis and Properties of para-Substituted NCN-Pincer Palladium and Platinum Complexes
✍ Martijn Q. Slagt; Gema Rodríguez; Michiel M. P. Grutters; Robertus J. M. Klein G 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 409 KB 👁 2 views

## Abstract A variety of __para__‐substituted NCN‐pincer palladium(II) and platinum(II) complexes [MX(NCN‐Z)] (M=Pd^II^, Pt^II^; X=Cl, Br, I; NCN‐Z=[2,6‐(CH~2~NMe~2~)~2~C~6~H~2~‐4‐Z]^−^; Z=NO~2~, COOH, SO~3~H, PO(OEt)~2~, PO(OH)(OEt), PO(OH)~2~, CH~2~OH, SMe, NH~2~) were synthesised by routes invol