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Paper-substrate room-temperature phosphorescence of phenothiazine derivatives enhanced by thallium(I) nitrate and surface-active agents

✍ Scribed by M.C. Garcia Alvarez-Coque; G. Ramis Ramos; A.M. O'Reilly; J.D. Winefordner


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
746 KB
Volume
204
Category
Article
ISSN
0003-2670

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✦ Synopsis


The effects of anionic, non-ionic, and cationic surfactants and thallium (I) nitrate on the papersubstrate room-temperature phosphorescence (RTP) of eleven phenothiazine derivatives are described. Enhancement factors within the range 1.5-10 are observed after addition of sodium dodecylsulfate, dodecyltrimethylammonium chloride and thallium (I ) nitrate. The influence of surfactant on phosphor characteristics as well as effects of moisture are discussed. Limits of detection were in the range 0.2-2 ng. Results are also reported for p-aminobenzoic acid, carbazole and o-terphenyl.