## Combined photoelectron and microwave techniques have been used to study the unstable species thioacetaldehyde, CHq,CHS, and thioacetone, (CH&CS. These species are produced when their re.spective cyclic trimers, 1,3,5-trimethyl s-trithiane and hexamethyl s-trithiane, are pyrolyzed. The trimer va
PAM analysis of the microwave spectra of thioacetic acid, CH3COSH and CH3COSD
β Scribed by Takashi Naito; Osamu Ohashi; Ichiro Yamaguchi
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 525 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Following the laboratory detection by Fourier transform microwave spectroscopy of the four new methylcyanopolyynes described in the accompanying paper by W. Chen et al. (J. Mol. Spectrosc. 1998), we detected two new methylpolyynes, CH3(C identical withC)4H and CH3(C identical withC)5H. The strongest
Two new methylpolyynes, CH 3 (C'C) 6 H (tridecahexayne) and CH 3 (C'C) 7 H (pentadecaheptayne), have been detected in a supersonic molecular beam by Fourier transform microwave spectroscopy. A total of 20 transitions of CH 3 (C'C) 6 H in the K Ο 0 and 1 rotational ladders and 8 transitions of CH 3 (
The microwave torsional-rotational spectra of gauche CH 3 CD 2 OH and CH 3 CD 2 OD have been identified, assigned, and analyzed up to 70 GHz. From the observed a-and c-dipole transitions, it has been possible to determine the effective rotational coefficients and the gauche tunneling energy of the h