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Palladium/Tris(tert-butyl)phosphine-Catalyzed Suzuki Cross- Couplings in the Presence of Water

✍ Scribed by Sha Lou; Gregory C. Fu

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 199 KB
Volume: 352
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.201000267

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✦ Synopsis

Abstract

Dipalladiumtris(dibenzylideneacetone)/tris(tert‐butyl)phosphonium tetrafluoroborate/potassium fluoride dihydrate [Pd~2~(dba)~3~/[HP(__t‐__Bu)~3~]BF~4~/KF⋅2 H~2~O] serves as a mild, robust, and user‐friendly method for the efficient Suzuki cross‐coupling of a diverse array of aryl and heteroaryl halides with aryl‐ and heteroarylboronic acids.

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