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Palladium(III)-Catalyzed Fluorination of Arylboronic Acid Derivatives

✍ Scribed by Mazzotti, Anthony R.; Campbell, Michael G.; Tang, Pingping; Murphy, Jennifer M.; Ritter, Tobias

Book ID
121205995
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
836 KB
Volume
135
Category
Article
ISSN
0002-7863

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Palladium-catalyzed synthesis of arylace
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Aryl amides were synthesized by the palladium catalyzed cross-coupling reaction of a-bromoacetamides with arylboronic acids in good yields. Both electron-donating and electron-withdrawing substituents on the aromatic ring are found to be compatible. The addition of Cu 2 O and PPh 3 was found to be e