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Palladium(II) Pyrazolin-4-ylidenes: Remote N-Heterocyclic Carbene Complexes and Their Catalytic Application in Aqueous Suzuki−Miyaura Coupling

✍ Scribed by Han, Yuan; Huynh, Han Vinh; Tan, Geok Kheng


Book ID
115453380
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
129 KB
Volume
26
Category
Article
ISSN
0276-7333

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Chiral and achiral pincer type palladium complexes bearing abnormal N-heterocyclic carbene ligands derived from 1,2,3-triazole are reported. Both complexes are effective as catalysts for non-asymmetric Suzuki coupling reaction for the synthesis of biphenyl derivatives. However, both the complexes fa