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Palladium(II)-mediated oxidative cyclization of N-carbamoyl aminoalkynes: a new route to γ-lactams

✍ Scribed by Huynh Dong Doan; Jacques Goré; Jean-Michel Vatèle

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 191 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01305-2

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✦ Synopsis

Transformation of N-carbamoyl or acetyl-4-trimethylsilyl-3-alkyn-l-amines to diversely substituted 2pyrrolidinones, via a Wacker-type reaction, is described.

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