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Palladium(II)-catalyzed hydroesterification of enol esters: Remarkable α-substituent effect upon regioselectivity

✍ Scribed by Kudo, K. ;Oida, Y. ;Mori, S. ;Komatsu, K. ;Sugita, N.

Book ID: 112685108
Publisher: Springer
Year: 1996
Tongue: English
Weight: 219 KB
Volume: 59
Category: Article
ISSN: 0133-1736
DOI: 10.1007/bf02067988

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Regioselective palladium (II) catalyzed hydroesterification of alkynes and alkynols using formate esters

✍ Bassam El Ali; Howard Alper 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 399 KB

The catalytic system Pd(OAc)Jdppb/PPhJp-TsOH catalyzes the hydroesterification of alkynes and alkynols with formate esters to give unsaturated esters in good yields and selectivities.