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Palladium(II)-Catalyzed Exchange and Isomerization Reactions. 17. Exchange of Chiral Allyl Alcohols with Hydroxide, Methoxide, and Phenyl at High [Cl-]. Stereochemistry of the Wacker Reaction

โœ Scribed by Hamed, Othman; Henry, Patrick M.; Thompson, Charles


Book ID
111984555
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
192 KB
Volume
64
Category
Article
ISSN
0022-3263

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Palladium(II)-catalyzed exchange and iso
โœ John W. Francis; Patrick M. Henry ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 894 KB

Further mechanistic studies on the PdCl,(pyridine)-catalytic system in aqueous solution are described using the tetrasubstituted allylic alcohol, (E)-2-methyl-d,-4-methyl-1,1,1,5,5,5-hexafluoro-3-penten-2-o1, 3a, and the trisubstituted allylic alcohol, (E)-4-Methyl-1,1,1,5,5,5-hexafluoro-3-penten-2-