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Palladium(II)-Catalyzed Enyne Coupling Reaction Initiated by Acetoxypalladation of Alkynes and Quenched by Protonolysis of the Carbon−Palladium Bond

✍ Scribed by Zhao, Ligang; Lu, Xiyan; Xu, Wei


Book ID
121430361
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
137 KB
Volume
70
Category
Article
ISSN
0022-3263

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Palladium(II)-catalyzed coupling reactio
✍ Guosheng Liu; Xiyan Lu 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 92 KB

Under divalent palladium catalysis, a highly regio-and stereoselective coupling reaction of alkynes with allyl halides initiated by cyclocarbopalladation of alkynes proceeded smoothly in the presence of excess halide ions. The reaction involves intramolecular carbopalladation, allylic compound inser