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Palladium(II)-Catalyzed 1,4-Addition of Arylboronic Acids to β-Arylenones for Enantioselective Synthesis of 4-Aryl-4H-chromenes

✍ Scribed by Takashi Nishikata; Yasunori Yamamoto; Norio Miyaura


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
105 KB
Volume
349
Category
Article
ISSN
1615-4150

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ChemInform Abstract: Palladium(II)-Catal
✍ Andreas Palmgren; Anna L. E. Larsson; Jan-E. Baeckvall; Paul Helquist 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB

Palladium(II)-Catalyzed 1,4-Oxidation of 2-Aryl-1,3-cyclohexadienes. Application to the Synthesis of (±)-Epibatidine and Analogues. -1,4-Chloroacetoxylation of arenes (I) in the presence of palladium(II) catalyst gives cis-cyclohexenes (III) with high regio-and stereoselectivity. These products are