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Palladium–dppb–borate-catalyzed regioselective synthesis of cinnamate esters by alkoxycarbonylation of phenylacetylene

✍ Scribed by Jimoh Tijani; Rami Suleiman; Bassam El Ali


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
192 KB
Volume
22
Category
Article
ISSN
0268-2605

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On the Regioselectivity Control in the P
✍ Giambattista Consiglio; Sylvia C. A. Nefkens; Carmelina Pisano; Fritz Wenzinger 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 German ⚖ 170 KB

## Abstract The regioselectivity of the hydro‐alkoxycarbonylation of methyl acrylate, methacrylate, and crotonate catalyzed by [PdCl~2~L~2~] complexes (L = phosphine ligands) can be largely controlled by variation of the ligands. PPh~3~, promotes preferential carbonylation at the α‐position, wherea