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Palladium imine and amine complexes derived from 2-thiophenecarboxaldehyde as catalysts for the Suzuki cross-coupling of aryl bromides

✍ Scribed by Julia Wiedermann; Kurt Mereiter; Karl Kirchner


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
257 KB
Volume
257
Category
Article
ISSN
1381-1169

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✦ Synopsis


A range of square-planar trans-dichloro palladium(II) complexes containing N-(2-thienylmethylene)-aniline and N-(2-thienylmethyl)-aniline derived ligands has been synthesized and characterized. The use of these complexes as catalysts for the Suzuki coupling of various aryl bromides and phenyl boronic acid has been examined.


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New Palladium Complexes with S- or Se-Co
✍ Ioannis D. Kostas; Barry R. Steele; Aris Terzis; Svetlana V. Amosova; Alexander 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 107 KB 👁 1 views

## Abstract Four palladium chelate complexes with S‐ or Se‐containing substituted salicylaldehyde Schiff‐base derivatives have been synthesized. Spectroscopic and crystallographic data indicate that, in the complexes, the deprotonated salicylaldehyde ligand is bound to the metal in an O,N,S (or Se)