✦ LIBER ✦

Palladium hydrides in organic synthesis. Reduction of aryl halides by sodium methoxide catalyzed by tetrakis(triphenylphosphine)palladium

✍ Scribed by Zask, Arie; Helquist, Paul

Book ID: 120969749
Publisher: American Chemical Society
Year: 1978
Tongue: English
Weight: 299 KB
Volume: 43
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00402a042

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Palladium hydrides in organic synthesis.

Palladium hydrides in organic synthesis. Reduction of aryl bromides by sodium formate catalyzed by tetrakis(triphenylphosphine)palladium

✍ Paul Helquist 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 128 KB

Earlier we reported a new method for the reduction of aryl halides to arenes with sodium methoxide as a source of hydride and tetrakisftriphenylphosphine)palladium (L) as a catalyst.

Selective reduction of alkynes catalyzed

Selective reduction of alkynes catalyzed by palladium acetate with sodium methoxide as the hydride source

✍ Li-Lan Wei; Li-Mei Wei; Wen-Bin Pan; Shiow-Piaw Leou; Ming-Jung Wu 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 91 KB

Treatment of internal alkynes with sodium methoxide in the presence of Pd(OAc) 2 and PPh 3 in methanol for 48 h gave the reduction products, alkenes or alkanes in good chemical yields. This reaction proceeds through a palladium methanolate complex, followed by b-hydride elimination and reductive eli

Selective Reduction of Alkynes Catalyzed

Selective Reduction of Alkynes Catalyzed by Palladium Acetate with Sodium Methoxide as the Hydride Source.

✍ Li-Lan Wei; Li-Mei Wei; Wen-Bin Pan; Shiow-Piaw Leou; Ming-Jung Wu 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 108 KB

Synthesis of phenylallenes in the reacti

Synthesis of phenylallenes in the reaction of phenyl-triisopropoxytitanium with propargylacetates catalyzed by tetrakis(triphenylphosphine)palladium

✍ A. N. Kasatkin; A. N. Kulak; G. A. Tolstikov 📂 Article 📅 1986 🏛 Springer 🌐 English ⚖ 89 KB

Reusable, Polymer-Supported, Palladium-C

Reusable, Polymer-Supported, Palladium-Catalyzed, Atom- Efficient Coupling Reaction of Aryl Halides with Sodium Tetraphenylborate in Water by Focused Microwave Irradiation

✍ Lin Bai; Jin-Xian Wang 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 206 KB 👁 3 views

## Abstract A rapid and efficient cross‐coupling reaction of sodium tetraphenylborate with aryl bromides was carried out in water at 120 °C in the presence of a polymer‐supported palladium catalyst and potassium carbonate under focused microwave irradiation. All four phenyl groups of sodium tetraph

A Facile Synthesis of Unsymmetrical Biar

A Facile Synthesis of Unsymmetrical Biaryls via Coupling Reaction of Aryl Halides with Sodium Tetraphenylborate Catalyzed by MCM-41-Supported Thioether Palladium(0) Complex.

✍ Jianying Li; Yixian Huang; Mingzhong Cai 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 20 KB 👁 2 views