Palladium complex catalyzed rearrangement of allylic sulfinates
โ Scribed by Lu Xi-Yan; Huang Yu-Jin
- Book ID
- 112058546
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- English
- Weight
- 141 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0256-7660
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๐ SIMILAR VOLUMES
We recently reported that mercuric trifluoroacetate was an effective catalyst for equilibrating carbamic esters of allylic alcohols at room temperature (1 8 3, X= NMe2). 394 Yields were uniformly high, and side-reactions (elimination, cyclization, &d sk2eta.l rearrangement) occasionally encountered
The Claisen rearrangement of ally1 vinyl ethers is catalyzed by PdCQ(CH3CN)Z. provided that alkyl substituents protect the vinyl ether double bond from coordination by the metal catalyst. [3,3]Sigmatropic rearrangements are very useful for the formation of C-C, C-O, C-N and C-S bonds. Besides the cl