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Palladium complex catalyzed rearrangement of allylic sulfinates

โœ Scribed by Lu Xi-Yan; Huang Yu-Jin


Book ID
112058546
Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
141 KB
Volume
2
Category
Article
ISSN
0256-7660

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๐Ÿ“œ SIMILAR VOLUMES


Palladium (II) - catalyzed rearrangement
โœ Larry E. Overman; Fredrick M. Knoll ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 191 KB

We recently reported that mercuric trifluoroacetate was an effective catalyst for equilibrating carbamic esters of allylic alcohols at room temperature (1 8 3, X= NMe2). 394 Yields were uniformly high, and side-reactions (elimination, cyclization, &d sk2eta.l rearrangement) occasionally encountered

Palladium(II)-catalyzed claisen rearrang
โœ J.L van der Baan; F Bickelhaupt ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 258 KB

The Claisen rearrangement of ally1 vinyl ethers is catalyzed by PdCQ(CH3CN)Z. provided that alkyl substituents protect the vinyl ether double bond from coordination by the metal catalyst. [3,3]Sigmatropic rearrangements are very useful for the formation of C-C, C-O, C-N and C-S bonds. Besides the cl