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Palladium complex catalyzed reactions of conjugated dienes I. Reaction of butadiene with aldehydes

✍ Scribed by R.M. Manyik; W.E. Walker; K.E. Atkins; E.S. Hammack

Book ID: 104249306
Publisher: Elsevier Science
Year: 1970
Tongue: French
Weight: 207 KB
Volume: 11
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)98597-1

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✦ Synopsis

Recently several reports have appeared concerning the reactions of butndiene with nucleophiles catalyzed by soluble palladium complexes (l-4).

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## Abstract The aminoalcohols **1**, react with 2 equivalents of butadiene in the presence of catalytic quantities of bis (acetylacetonato)palladium/triphenylphosphine to give exclusively the corresponding __N__‐octadienyl amninoalcohols. In the presence of excess butadiene, subsequent __O__‐octadi